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Module 2: Characteristics of Gases - Oxygen Basis Conversions - Practice Problems

Instructions:
Work these problems on a sheet of paper and check your answers against those provided below.

Helpful Calculators:
The following calculators may be useful in solving these problems. You can access them either from the "Calculators" button on the screen or from the links below.

Correction of Concentration (Measured Standard O2 Basis)
Correction of Concentration (Wet Dry Basis)
Concentration Converter (Minor Gas Constituents)

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Q icon #1
The concentration of formaldehyde in a gas stream is measured at 1.3 ppmvd. The gas stream oxygen concentration during the measurement was 13.6%. What is the formaldehyde concentration expressed on a 7% basis?

A icon
Answer: 2.48 ppmvd

Solution:

practice equation 1

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Q icon #2
The concentration of benzene has been measured at 100 µg/m3. What is the concentration expressed on an 11% O2 basis if the measured oxygen concentration in the gas stream was 3.1%?

A icon
Answer: 55.6 µg/m3

Solution:

practice equation 2

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Q icon #3
The concentration of sulfuric acid vapor in a gas stream has been measured as 7 ppm. What is this concentration expressed at 7% O2 if the measured oxygen concentration was 10%?

A icon
Answer: practice equation 3

Solution:
practice equation 3a

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Q icon #4
An emission test has determined that the emissions of hydrogen chloride (HCl) vapor from an industrial process are 10 mg/m3. Is the source in compliance with the regulatory limit of 15.0 mg/Dm3 at 7% oxygen if the following conditions existed during the test?

practice equation 4

A icon
Answer: Yes, the source is in compliance with the hydrogen chloride emission limit of 15.0 mg/Dm3) at 7% oxygen.

Solution:
  1. Convert the emissions data to a dry basis.
    practice equation 4(1)

  2. Convert the dry concentration to a 7% oxygen basis.
    practice equation 4(2)

The source is in compliance with the emission limit of 15.0 mg/Dm3 at 7% O2.

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Q icon #5
An SO2 emission test has indicated that the outlet concentration from a wet scrubber is 5 ppmvd. Is the wet scrubber meeting the manufacturer's guarantee of 25,000 µg/m3 at 7% oxygen? The oxygen in the gas stream during the test was 11.5%.

A icon
Answer: Yes, the scrubber SO2 emissions satisfy the manufacturer's guarantee. The SO2 concentration is 19,700 µg/m3 at 7% oxygen level.

Solution:
  1. Convert the SO2 ppmvd level to 7% oxygen.
    practice equation 5(1)

  2. Convert the SO2 concentration at 7% oxygen from ppm to micrograms per cubic meter.
    practice equation 5(2)
Where: MW of SO2 is the molecular weight of SO2 expressed as lbm/lb mole

practice equation 5(2a)

Yes, the scrubber SO2 emissions satisfy the manufacturer's guarantee. The SO2 concentration at 7% oxygen level is less than 25,000 µg/m3.

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