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Fish Contaminants

Overview

Health Concerns from fish consumption

Contaminant Concentrations in the Great Lakes

Fish Advisories

Reports & Links

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 Great Lakes Monitoring Program Collection Site graphic

The Great Lakes Fish Monitoring and Surveillance Program (GLFMSP) consists of two separate programs, the Open Lakes Trend Monitoring Program and the Emerging Chemical Surveillance Program.  The Sport Fish Fillet Monitoring Program was recently eliminated.  The Open Lake Trend Monitoring Program was designed to examine the health of fish and fish-consuming wildlife through trend analysis while the Emerging Chemical Surveillance Program has been designed to screen for emerging chemicals in fish tissue according to their persistent, bioaccumulative, and/or toxic chemical
properties to help identify chemicals to be added to the Open Lakes Trend Monitoring Program and to inform State Fish Advisory Programs.

Open Lakes Trend Monitoring Program  - This component is directed at monitoring contaminant trends in the open waters of the Great Lakes (using fish as biomonitors), and assessing the overall effects of toxics on fish and fish consuming wildlife .  The program provides for collection and analysis of lake trout (walleye in Lake Erie) from each of the Great Lakes.  Fish samples are collected in the fall of the year, using fish of similar size to reduce the impact of size variation on contaminant trend data.  Fish samples are then analyzed for several different contaminants, including PCBs, toxaphene, chlordanes, nonachlors, and other organochlorine compounds.  Whole fish are analyzed , including parts not usually eaten by humans, such as the liver and bones, because wildlife consume the entire fish.  Contaminants, such as PCBs, toxaphene, chlordanes, nonachlors, and other organochlorine compounds are routinely monitored in Great Lake’s top predator fish.  Emerging contaminants, such as PBDEs were recently added to the list of contaminants to be analyzed.


Emerging Chemical Surveillance Program  is directed at screening for emerging chemicals in fish tissue according to their persistent, bioaccumulative, and/or toxic chemical properties. This program has utilized samples collected for the Open Lakes Monitoring Program and mega composites from each lake (representing all samples from a given lake) to determine the presence of a contaminant of interest in top predator fish, help identify and guide State and Federal monitoring programs in the development of their analyte lists and priority setting, and to inform the Open Lakes Monitoring Program to allow for the incorporation of contaminants of concern into the routine analyte list. Retrospective analysis may be conducted upon on archived samples if a chemical of interest is identified.  

Prioritization for Emerging Chemicals to be included in this portion of the program are identified in a number of ways.

Great Lakes Fish Monitoring Program Analyte List

Analyte

MDL, ng/g

PCB congeners

0.002 – 1.0

PCB co-planars

0.002 – 1.0

Hexachlorobenzene

1

Octachlorostyrene

0.83

δ-BHC (Lindane)

0.606

α-BHC

4.7

Dieldrin

0.44

Heptachlor epoxide b

0.52

Cis-chlordane

1.814

Trans-chlordane

0.488

Cis-nonachlor

1.95

Trans-nonachlor

1.48

Oxychlordane

1.94

pp,-DDT

0.66

pp,-DDE

0.74

pp,-DDD

0.52

Endrin

2.86

Mirex (Lake Ontario only)

1.52

Toxaphene&homologs

24.6

PBDEs

0.001 – .10

Hg

0.521

Fraction lipid

5%

*PCDD/Fs

0.3 - 25

*PCNs

0.2 – 6.0

*Dacthal

1.0

*PBB-153

0.1 - .2

*PFOS

0.5

*A scan for specified list of additional analytes, such as perfluorinated compounds, musk fragrances, APEs, pharmaceuticals and other personal care products (pseudo-persistence), other flame retardants, etc., will be conducted.

 


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