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Summaries of Arsenic Publications

Regulations on the Disposal of Arsenic Residuals from Drinking Water Treatment Plants

EPA 600-R-00-025

As with other production processes, water treatment systems produce a product and a residual of that product. With the passage of the various federal statues, restrictions have been placed on the discharge of residuals to water bodies and onto land. This report summarizes federal regulations and selected state regulations that govern the management of residuals produced by small drinking water treatment systems removing arsenic from drinking water.

Arsenic is a naturally occurring contaminant in ground water and many small water treatment facilities use ground water as their primary source of water. Under the Safe Drinking Water Act (SDWA), a maximum contaminant level (MCL) of 0.05 mg/L has been established for arsenic in drinking water. Under the 1996 SDWA Amendments, the EPA is required to develop a revised arsenic regulation by January 2001. Concerns have been raised as to the technical feasibility and regulatory implication of a more stringent arsenic MCL on the disposal of the residuals from arsenic removal processes.

This document reports on five water treatment processes known to be effective for arsenic removal from small ground water systems. The five processes are anion exchange, activated alumina adsorption, iron/manganese removal, media adsorption, and membrane processes. For each technology, a brief description is provided of the treatment process along with a discussion of the residual production characteristics.

An overview is provided of the federal regulations that apply to the management of residuals, with a focus on arsenic removal residuals. The purpose of this overview is to provide guidance to water suppliers on the federal regulatory requirements of residuals management to better evaluate compliance of existing practices and to plan for needed changes in treatment plant operations. Specific disposal methods are summarized by the form of the residuals including liquid residuals (direct discharges, indirect discharges, underground injection, and land disposal) and solid/sludge residuals (solid waste landfill, hazardous water landfill, lagoons, reuse of hazardous waste, reuse of solid waste, and off-site disposal) and the method in which the residuals are managed. Federal regulations summarized include the Clean Water Act (NPDES, Pretreatment), SDWA (Underground Injection Control and lagoons), and Resource Conservation and Recovery Act (Subtitles C/D). In addition to the federal regulations that impact the management of arsenic drinking water treatment residuals, regulations imposed by seven states were also reviewed. The seven states (Arizona, California, Maine, Nebraska, New Mexico, Nevada, and Pennsylvania) were chosen based on arsenic occurrence and regional representation. The review of the state regulations also focused on characterizing the requirements that apply to different management options available for liquid and solid residuals generated by treatment systems that remove arsenic from drinking water. It was found that many components of the state regulatory programs were generally consistent with the federal minimum requirements. However, the state programs differed from federal program requirements and each other in several aspects including surface water quality standards applicable to control the amount of arsenic in direct discharges of liquid effluent, the local limits that specify how much arsenic may be discharged to a sanitary sewer system, the regulation of solid waste landfills, the protection of ground water resources, and the regulation of land application activities.

Arsenic Removal from Drinking Water by Coagulation/filtration and Lime Softening Plants

EPA 600-R-00-063

This report documents treatment plant information as well as results of sampling and analysis at two coagulation/filtration plants (referred to in this document as Plants A and B) and one lime softening plant (referred to as Plant C). The objective of sampling and analysis was to evaluate the effectiveness of the water treatment plants to consistently remove arsenic (As) from source water. Additionally, data were collected in this study to evaluate the characteristics of the residuals produced by the treatment processes.

The study was divided into three phases: source water sampling, preliminary sampling, and long-term evaluation. The first phase, source water sampling, was conducted to evaluate source water characteristics at each plant. The second phase, preliminary sampling, consisted of a four-week sampling period to refine procedures prior to implementing the long-term evaluation phase. The third phase, long-term evaluation, consisted of weekly sample collection and analysis for approximately 1 year. Sludge samples also were collected at each facility during a single sampling
event from settling lagoons/ponds during a two-month period. Samples of recycle supernatant water (Plant A) and supernatant discharge water (Plants B and C) were collected monthly beginning in November 1998 and continuing until June 1999. Long-term evaluation of Plants A and B demonstrated that conventional coagulation/filtration can consistently achieve low levels of arsenic in the treated water (i.e., less than 5 μg/L). The total arsenic concentrations at Plant A were reduced by an average of 52%, which represents a decrease of average arsenic concentrations
from 7.5 μg/L in the source water to 3.5 μg/L in the finished water. Average total arsenic removal efficiency at Plant B was 79%, with an average source water concentration of 19.1 μg/L and an average finished water concentration of 4.0 μg/L. Adsorption and coprecipitation of As(V) with iron and aluminum flocs are believed to have been the primary arsenic removal mechanisms at these plants.

The lime softening facility, Plant C, was not able to consistently reduce arsenic to low levels in treated water. The average total arsenic concentration in Plant C source water was 32.0 μg/L, and the lime softening plant reduced the average total arsenic concentration to 16.6 μg/L in the finished water, which equals a 45% removal efficiency. As(III) was the primary species of soluble arsenic in the raw water and was almost completely oxidized to As(V) as a result of two chlorination steps that occurred prior to softening and prior to filtration. The primary mechanism of arsenic removal
was likely adsorption and coprecipitation of As(V) with iron that was present in the source water. Plant C operated at a pH of 9.6, a level at which arsenic removal by coprecipitation with calcium carbonate is reported to be less than 10% (Sorg and Logsdon, 1978; McNeill and Edwards, 1997b).

None of the sludge samples collected at Plants A, B, and C qualified as a hazardous waste based on Toxicity Characteristic Leaching Procedure (TCLP) testing for metals. Therefore, nonhazardous waste landfills should be able to accept the sludge generated by these treatment processes.

Arsenic Removal from Drinking Water by Iron Removal Plants

EPA 600-R-00-086

This report documents treatment plant information as well as results of sampling and analysis at two iron removal plants (referred to as Plants A and B). The objective of sampling and analysis was to evaluate the effectiveness of the water treatment plants to consistently remove arsenic (As) from source water. Additionally, data were collected in this study to evaluate the chemical characteristics of residuals produced by the treatment processes.

The study was divided into three phases: source water sampling, preliminary sampling, and longterm evaluation. The first phase, source water sampling, was conducted to evaluate source water characteristics at each plant. The second phase, preliminary sampling, was initiated at Plant A in April 1998 and at Plant B in May 1998. This phase consisted of a four-week sampling period to
refine procedures for subsequent events during the third phase. The third phase, long-term evaluation, consisted of weekly sample collection and analysis beginning in June 1998 and continuing through June 1999 at Plant A and through December 1998 at Plant B. Plant personnel conducted all sampling during the long-term evaluation phase and Battelle coordinated sampling logistics. Sludge samples also were collected at Plant A during a single sampling event from an outdoor settling pond in November 1998. Samples of supernatant discharge (Plant A) and recycle supernatant (Plant B) were collected monthly beginning in November 1998 and continuing until June 1999 at Plant A and until January 1999 at Plant B.

Results from the long-term evaluation phase were varied regarding the ability of the iron removal process to consistently achieve low-level arsenic concentrations (e.g., <5 μg/L in the finished water). The total arsenic concentrations at Plant A were reduced by an average of 87%, which represents a decrease in average arsenic concentration from 20.3 μg/L to 3.0 μg/L. Adsorption and coprecipitation with iron hydroxide precipitates are believed to be the primary arsenic removal mechanisms. The total arsenic concentrations at Plant B were reduced by an average of 74%, which represents a decrease in average arsenic concentration from 48.5 μg/L to 11.9 μg/L. At Plant B, it appeared that only the particulate arsenic in the source water was removed. This particulate arsenic was most likely associated with the oxidized iron particles present in the source water (i.e., arsenic sorbed onto iron particles). The primary difference in arsenic removal efficiency at Plants A and B is believed to be the amount of iron in the source water. Source water at Plant A averaged 2,284 μg/L of iron, while Plant B averaged 1,137 μg/L. Increasing the iron in the source water at Plant B using a coagulant, such as ferric chloride, would likely enable Plant B to onsistently
achieve lower levels of arsenic. None of the sludge samples collected at Plant A qualified as a hazardous waste based on the Toxicity Characteristic Leaching Procedure (TCLP) test for metals. Therefore, nonhazardous waste landfills should be able to accept the sludge generated by this treatment facility. Stricter hazardous waste classification regulations in some states, such as California, on total arsenic concentrations in solid waste also were met at Plant A. Sludge samples were not collected at Plant B; however, analytical results were provided from a 1994 sludge sampling event.

Arsenic Removal from Drinking Water by Ion Exchange and Activated Alumina Plants

EPA 600-R-00-088

This report documents treatment plant information as well as results of year-long sampling and analysis at two ion exchange (IX) plants (referred to as Plants A and B) and two activated alumina (AA) plants (referred to as Plants C and D), with capacities varying from 800 to 3,000 gallons per day (gpd). The objective of sampling and analysis was to evaluate the performance of the full-scale water treatment plants to consistently remove arsenic from source water. Additionally, data were collected to evaluate the chemical characteristics of residuals produced by these treatment processes.

The study was divided into three phases: source water sampling, preliminary sampling, and long-term evaluation. Source water sampling was conducted to evaluate source water characteristics at each plant. Preliminary sampling was initiated in August 1998 and consisted of four sampling events conducted at each facility on either a weekly or biweekly basis to refine procedures for subsequent events during the third phase. Long-term evaluation consisted of weekly or biweekly sampling at
each facility from September 1998 to September 1999. Samples from resin regeneration were collected at Plant A from March to June 1999. Spent AA samples were collected at Plants C and D during the media change-out events in December 1998 and May 1999, respectively. Results from the long-term evaluation demonstrated that both the IX and AA systems are capable of achieving arsenic levels of less than 5 μg/L in the treated water, provided that the IX resin was regenerated or the AA medium was changed out before arsenic breakthrough occurred. The two IX systems had inlet arsenic concentrations between 45 and 65 μg/L [primarily As(V)]. When Plant A was operated beyond 3,000 to 3,200 bed volumes (BV) of water, arsenic chromatographic peaking occurred. Arsenic breakthrough was not observed at Plant B where an average 97% of removal efficiency was achieved, leaving only 0.8 to 4.5 μg/L arsenic in the finished water. Both AA systems consisted of two parallel treatment trains with a roughing AA column followed by a polishing column in each train. The systems operated on a media throwaway basis. The average arsenic removal efficiencies achieved at Plants C and D were 87% and 98%, respectively. The raw water at Plant C (34 to 76 μg/L total arsenic) contained approximately 0.3 to 28.8 μg/L As(III), which was nearly completely removed, even though no oxidation treatment was provided. The water at Plant D contained slightly higher total arsenic concentrations (53.3 to 87 μg/L) but no As(III), which was consistently removed to less than 5 μg/L in the finished water. The AA media in the roughing tanks were exhausted and disposed of about every 1 to 1.5 years after treating approximately 9,600 BV at Plant C and 5,260 BV at Plant D. The regeneration process at Plant A recovered from 67 to 86% of arsenic from the spent brine. The spent AA at Plants C and D passed the Toxicity Characteristic Leaching Procedure (TCLP) test for metals including arsenic, and therefore was disposed of as nonhazardous waste.

Laboratory Study on the Oxidation of Arsenic III to Arsenic V

EPA 600-R-01-021

A one-year laboratory study was performed to determine the ability of seven oxidants to oxidize As(III) to As(V). These included chlorine, permanganate, ozone, chlorine dioxide, monochloramine, a solid-phase oxidizing media, and 254 nm ultraviolet light. Chlorine and permanganate rapidly oxidized As(III) to As(V) in the pH range of 6.3 to 8.3. Dissolved manganese, dissolved iron, sulfide and TOC slowed the rate of oxidation slightly, but essentially complete oxidation was obtained in less than one minute with chlorine and permanganate under all conditions studied.

In the absence of interfering reductants, ozone rapidly oxidized As(III). Although, dissolved manganese and dissolved iron had no significant effect on As(III) oxidation, the presence of sulfide considerably slowed the oxidation reaction. The presence of TOC had a quenching effect on As(III) oxidation by ozone, producing incomplete oxidation at the higher TOC concentration studied. Only limited As(III) oxidation was obtained using chlorine dioxide, which was probably due to the presence of chlorine (as a by-product) in the chlorine dioxide stock solutions. The reason for the ineffectiveness of chlorine dioxide was not studied.

Preformed monochloramine was ineffective for As(III) oxidation, whereas limited oxidation was obtained when monochloramine was formed in-situ. This showed that the injected chlorine probably reacted with As(III) before being quenched by ammonia to form monochloramine. Filox, a manganese dioxide-based media, was effective for As(III) oxidation. When dissolved oxygen (DO) was not limiting, complete oxidation was observed under all conditions studied. However, when DO was reduced, incomplete oxidation was obtained in the presence of interfering reductants. The adverse effect of interfering reductants was completely eliminated by either (a) supplying enough DO or (b) increasing the contact time. In addition to oxidizing As(III), the Filox media also removed some arsenic by adsorption, which diminished greatly as the media came into equilibrium with the As(III)-spiked synthetic water.

UV light alone (254 nm) was not very effective for As(III) oxidation. Significant oxidation was observed only at very low flow rates representing 0.6 - 2.5% of the rated capacities of the two UV sterilizer units tested. However, as reported in a patented process, complete oxidation by UV light was observed when the challenge water was spiked with 1.0 mg/L sulfite.

Treatment of Arsenic Residuals from Drinking Water Removal Processes

EPA 600-R-01-033

The drinking water MCL was recently lowered from 0.05 mg/L to 0.01 mg/L. One concern was that a reduction in the TCLP arsenic limit in response to the drinking water MCL could be problematic with regard to disposal of solid residuals generated at arsenic removal facilities. This project focused on developing a short-list of arsenic removal options for residuals produced by ion exchange (Ion Ex), reverse osmosis (RO), nanofiltration (NF), activated alumina (AA), and iron removal processes. Both precipitation and adsorption processes were evaluated to assess their arsenic removal effectiveness.

In precipitation tests, ferric chloride outperformed alum for removal of arsenic from residuals by sedimentation, generally resulting in arsenic removals of 88 to 99 percent. Arsenic removal from the high alkalinity ion exchange samples was poorer. The required iron-to-arsenic molar ratio for best removal of arsenic in these screening tests varied widely from 4:1 to 191:1, depending on residuals type, and best arsenic removal using ferric chloride typically occurred between pH 5.0 and 6.2. Polymer addition typically did not significantly improve arsenic removal using either coagulant. Supernatant total arsenic levels of 0.08 mg/L or lower were attained with ferric chloride precipitation for membrane concentrates and residuals from iron removal facilities compared to an in-stream arsenic limit of 0.05 mg/L in place in some states. Settling alone with no coagulant also effectively removed arsenic from iron removal facility residuals. Even with ferric chloride dosages of 50 to 200 mg/L applied to ion exchange regenerants, supernatant arsenic levels after treatment were 1 to 18 mg/L. Required iron-to-arsenic molar ratios developed in precipitation work could be used by utilities as guidelines for establishing coagulant dose needs to meet in-stream standards, and to develop preliminary treatment costs.

Adsorption tests demonstrated the potential for different types of media and resins to remove arsenic from liquid residuals, but did not assess ultimate capacity. Overall, the iron-based granular ferric hydroxide media evaluated in testing outperformed the aluminum-based media and ion exchange resin for removal of arsenic. However, activated alumina and the iron-based media provided comparable arsenic removals of close to 100 percent with an empty bed contact time (EBCT) of 3-min for most of the membrane concentrates and the settled iron removal facility residuals. Removal of suspended solids was key to the success of adsorption for spent filter backwash water and clarifier flush residuals. Arsenic breakthrough occurred very rapidly for the ion exchange samples and for one RO concentrate, all of which had an alkalinity of more than 1,000 mg/L (as CaCO3). This again suggests that alkalinity significantly interferes with adsorption of arsenic. Based on this work, use of adsorption media for treatment of arsenic-laden water plant residuals merits further exploration.

Of all of the residuals streams tested, Ion Ex regenerants were the most difficult to treat using precipitation or adsorption. Disposal of supernatant streams resulting from treatment of arsenic-laden residuals from ion exchange plants could pose a major challenge. TCLP arsenic levels in all residuals generated in this work and in full-scale solid media samples were far below the regulatory limit of 5 mg/L, and in fact were below 0.5 mg/L.

Oxidation of As(III) by Aeration and Storage

EPA 600-R-01-102

A study of the effects of aeration and storage on the oxidation of arsenic(III) was undertaken at three utilities in the U.S. to establish the engineering significance of aeration as a potential pre-treatment method for arsenic removal. Aeration has been referred to in the literature as a possible useful pre-treatment method to ensure that arsenic in is the arsenic(V) state before subsequent removal by any of several treatment processes. Since aeration a common process for treating groundwater for iron oxidation, radon, volatile organics, carbon dioxide, and hydrogen sulfide, it is reasonable to investigate its effectiveness for arsenic(III) oxidation.

The results of this study clearly establish that aeration and aerobic storage do not oxidize arsenic(III). The major conclusion is that aeration is not effective for this purpose and should not be relied upon or expected to contribute to the oxidation of arsenic(III). One of the test sites in this study clearly showed that arsenic(III) is significantly removed by the oxidation and precipitation of iron, but this should not be attributed to an oxidation of arsenic(III) to arsenic(V) by dissolved oxygen. Past research has established that iron precipitation can be partially effective for the adsorptive removal of arsenic(III), and this is the likely explanation for the apparent drop in arsenic(III) at the site that had high iron.

The effect of iron precipitation on the removal of arsenic was also present in the long term storage of aerated water in this study. When all of the iron (initial iron at 2.7 mg/L) precipitated from the quiescent storage water, the remaining aqueous total arsenic was entirely dissolved and in the arsenic(V) state. The aqueous arsenic(III) was below detection and apparently completely removed or converted by the insoluble iron. Even in this case it is doubtful if DO was responsible for any oxidation of arsenic(III), because the loss directly correlated to the loss of iron precipitate and no other instance of arsenic(III) oxidation occurred at the other sites. In summary, the data supported the fact that iron is extremely important in the removal of arsenic(III), but did not support the idea that arsenic(III) is oxidized by aeration. This is true at least for the conditions used in this study.

While the subtleties of the results are interesting, especially for the site with high iron, it is important to emphasize the original objective of this study, which was to establish if typical aeration and storage methods could oxidize arsenic(III). Based upon the results of this study, it is concluded that aeration does not oxidize arsenic(III) and that subsequent storage for up to five days does not result in arsenic(III) oxidation. Dissolved oxygen should not be considered as a candidate for arsenic(III) oxidation; however, aeration will continue to be considered a very effective process for the oxidation of iron. In that way, aeration can be said to be effective in bringing about the removal of As via the oxidative precipitation of iron.

Design Manual: Removal of Arsenic from Drinking Water by Adsorptive Media

EPA 600-R-03-019

This design manual is an in-depth presentation of the steps required to design and operate a water treatment plant for removal of excess arsenic from drinking water using the adsorptive media process. This treatment process is very reliable, simple and cost-effective. Several adsorptive media products are available in the market-place that have successfully demonstrated their capability to remove arsenic from drinking water to levels well below the revised MCL, 0.010 mg/L. Other new products continue to be developed. The adsorptive media products are preferential for the removal of arsenic over other competing ions. Therefore, unless a water system requires treatment capability for removal of other suspended or dissolved contaminants, the adsorptive media treatment method merits evaluation.

The adsorptive media process is implemented with operational options which vary with the product selected. For water systems that are primarily concerned with financial feasibility, capital and operating costs, each operational option along with each available adsorptive media product should be evaluated. This design manual provides the methods for competently performing each evaluation. The arsenic removal capacity of some adsorptive media products, such as activated alumina, are very sensitive to the pH of the water passing thru treatment. Others, such as iron-based products, are not. Treatment processes incorporating pH adjustment capability require careful handling and storage of corrosive chemicals (acid and caustic). Some adsorptive media products, such as activated alumina, are capable of being chemically regenerated for repetition of treatment cycles using the same corrosive chemicals as those used for pH adjustment in the treatment process. Regeneration is not recommended for other adsorptive media products. Whether or not pH of water being treated is adjusted, the adsorptive media can be replaced in place of regeneration upon exhaustion of arsenic capacity. This design manual presents the information necessary to design and operate treatment systems for any combination of operational options and for any adsorptive media. It also discusses the capital and operating costs including the many variables which can raise or lower costs for identical treatment systems.

Design Manual: Removal of Arsenic from Drinking Water by Ion Exchange

EPA 600-R-03-080

This design manual is an in-depth presentation of the steps required to design and operate a water treatment plant for removing arsenic in the As(V) form from drinking water using the anion exchange process. Because As(III) occurs as an uncharged anion in ground water in the pH range of 6.5 to 8, the process will not remove As(III) unless it is first oxidized to As(V). The manual also discusses the capital and operating costs, including many of the variables that can raise or lower costs for identical treatment systems.

The anion exchange treatment process is very reliable, simple, and cost-effective. The treatment process removes arsenic using a strong base anion exchange resin in either the chloride or hydroxide form, with chloride the preferred form because salt can be used as the regenerant. The process preferentially removes sulfate over arsenic; and, therefore, as the sulfate increases in the raw water, the process becomes less efficient and more costly. Furthermore, because sulfate occurs in significantly higher concentrations than arsenic, treatment run lengths are dependent almost entirely on the sulfate concentration of the raw water. The ion exchange process is a proven efficient and cost-effective treatment method for removing As(V) from water supplies with low sulfate levels.

The configuration of an anion exchange system for As(V) removal can take several forms. The method presented in this design manual uses three vertical cylindrical pressure vessels operating in a downflow mode. Two of the three treatment vessels are piped in parallel to form the primary arsenic removal stage. The third treatment vessel is piped in series in the lag position. In the primary stage, raw water flows through one of the two treatment vessels while the second vessel is held in the standby position. When the treatment capacity of the first vessel approaches exhaustion, it is removed from service and replaced by the second primary stage vessel. While out of service, the first vessel is regenerated and placed in the standby position. The role of the third treatment vessel in the lag position is to ensure that any arsenic that breaks (peaking) through one of the lead vessels does not enter the distribution system. Although this design concept results in higher capital costs, it prevents high arsenic concentrations in the treated water, if operated properly.

Capital Costs of Arsenic Removal Technologies Demonstration Program Round 1

EPA 600-R-04-201

On January 18, 2001, the U.S. Environmental Protection Agency (EPA) finalized the maximum contaminant level (MCL) for arsenic at 0.01 mg/L. EPA subsequently revised the rule text to express the MCL as 0.010 mg/L (10 μg/L). The final rule requires all community and non-transient, non-community water systems to comply with the new standard by February 2006. In October 2001, the EPA announced an initiative for additional research and development of cost-effective technologies to help small community water systems (<10,000 customers) meet the new arsenic standard, and to provide technical assistance to operators of small systems in order to reduce compliance costs.

As part of this Arsenic Rule Implementation Research Program, EPA’s Office of Research and Development (ORD) proposed a project to conduct a series of full-scale, long-term, on-site demonstrations of arsenic removal technologies, process modifications, and engineering approaches applicable to small systems in order to evaluate the efficiency and effectiveness of arsenic removal systems at meeting the new arsenic MCL. For the Round 1 demonstration study, the selected arsenic treatment technologies include nine adsorptive media systems, one ion exchange system, one coagulation/filtration system, and one process modification. The adsorptive media systems use four different adsorptive media, including three iron-based media, i.e., ADI’s G2, Severn Trent and AdEdge’s E33, and USFilter’s GFH, and one iron-modified activated alumina media, i.e., Kinetico’s AAFS50 (a product of Alcan). Since the inception of the project, 10 of 12 systems have been installed, with flowrates at all systems ranging from 37 to 640 gpm.

A key objective of the long-term demonstration project is to determine the cost-effectiveness of the technologies. This report provides a brief description of each of the 12 Round 1 demonstration sites and the respective technologies being evaluated. Capital costs were organized into three categories— equipment, engineering, and installation—and then summed to arrive at a total capital investment cost for each system. Operations and maintenance (O&M) costs associated with the treatment systems are not yet available; however, vendor-supplied estimates on media replacement costs also are provided in this report.

Excluding the cost for one system modification site, the total capital investment costs range from $90,757 to $305,000, and vary by flowrate, system design, material of construction, monitoring equipment, and specific site conditions. Based on a 3% interest rate and a 20-year return period, the unit costs of the total capital investment range from $0.03 to $0.79 per 1,000 gallons of water treated. In general, the unit cost decreases as the size of a treatment system increases. The equipment costs for the treatment systems range from $66,235 to $218,000, representing 54 to 80% of the total capital investment cost. Engineering costs for the treatment systems range from $4,907 to $50,659, accounting for 5 to 22% of the total capital investment with an average of 12%. Installation costs for the treatment systems range from $13,150 to $77,574, which accounts for 12 to 34% of the total capital investment with an average of 22%.

Finally, building cost information obtained from the host facilities also is provided in the report. Building costs range from $3,700 to $186,000, varying according to differences in location, size, design, material of construction, and choice of construction contractor.

Technology Selection and System Design, USEPA Arsenic Demonstration Program Round 1

EPA 600-R-05-001

On January 18, 2001, the U.S. Environmental Protection Agency (EPA) finalized the maximum contaminant level (MCL) for arsenic at 0.01 mg/L. EPA subsequently revised the rule text to express the MCL as 0.010 mg/L (10 μg/L). The final rule requires all community and non-transient, non-community water systems to comply with the new standard by February 2006. In October 2001, EPA announced an initiative for additional research and development of cost-effective technologies to help small community water systems (<10,000 customers) meet the new arsenic standard, and to provide technical assistance to operators of small systems in order to reduce compliance costs.

As part of this Arsenic Rule Implementation Research Program, EPA’s Office of Research and Development (ORD) proposed a project to conduct a series of full-scale, long-term, on-site demonstrations of arsenic removal technologies, process modifications, and engineering approaches applicable to small systems in order to evaluate the efficiency and effectiveness of arsenic removal systems at meeting the new arsenic MCL. For the Round 1 demonstration study, the selected arsenic treatment technologies include nine adsorptive media systems, one ion exchange system, one coagulation /filtration system, and one process modification. The adsorptive media systems use four different adsorptive media, including three iron-based media (i.e., ADI’s G2, Severn Trent and AdEdge’s E33, and USFilter’s GFH), and one iron-modified activated alumina media (i.e., Kinetico’s AAFS50, a product of Alcan). The flowrate of these systems ranges from 37 to 640 gallons per minute (gpm).

This report provides the source water quality characteristics at each of the 12 demonstration sites and the general rationale used to select the technologies for demonstration at each site. Information on the design and operation of each treatment system also is presented. The selection of the technologies for demonstration at each location was a cooperative decision made by the water system, state, and EPA. Many factors were considered in the selection process, including water quality, residual production and disposal, complexity of system operation, and costs. The selection of the adsorptive media and pretreatment methods depended on a number of factors that affect the system performance, including arsenic concentration and speciation, pH, and the presence of competing anions, as well as media-specific characteristics such as costs, media life, and empty-bed contact time (EBCT) requirements.

Using DWSRF Funds to Comply with the New Arsenic Rule

EPA 816-F-02-004

The Drinking Water State Revolving Fund (DWSRF) program was established by the 1996 Safe Drinking Water Act (SDWA) Amendments and authorizes grants to states to capitalize revolving loan funds. The states provide low-interest loans to eligible systems for infrastructure improvements needed to ensure compliance with the SDWA and protect public health. The DWSRF program can play a significant role in helping systems, especially small systems, to meet the challenges of complying with new drinking water standards.

The Environmental Protection Agency (EPA) published revisions to the Arsenic Rule in 2001 which further reduce exposure to arsenic in drinking water by adopting a new arsenic maximum contaminant level (MCL) of 10 ppb. The new MCL will impose a financial burden on some water systems. The DWSRF can provide assistance to systems to help ease this burden, increase compliance, and protect public health.

Using DWSRF Funds to Comply with the New Arsenic Rule (259 K PDF File, 4pgs)

Rural Development-Rural Utilities Service, Loan, and Grant Program: Fact Sheet

EPA 816-F-03-009

USDA/Rural Development/Rural Utilities Service (RUS) administers water and wastewater loan and grant programs to improve the quality of life and promote economic development in Rural America. These programs were previously administered by the Farmers Home Administration (FmHA)

Rural Development-Rural Utilities Service, Loan, and Grant Program: Fact Sheet (129 K PDF File, 1pg)

Implementation Guidance for the Arsenic Rule - Drinking Water Regulations for Arsenic and Clarifications to Compliance and New Source Contaminants Monitoring

EPA 816-K-02-018

The final Implementation Guidance for the Arsenic Rule is based on the final rule published in the Federal Register on January 22, 2001. It incorporates comments received on the previous draft implementation guidances, and from the training sessions on the arsenic rule held throughout the country. The guidance summarizes key sections of the Proposed Rule and provides a "how to approach" for EPA Regions and States to implement the regulation. It contains an explanation of the rule's requirements and guidance for preparing State primacy revision applications. The document incorporates comments received from Regions, States, technical assistance providers, water systems, and others.

Final Guidance (515 K PDFFile, 83 pgs)

Complying With the Revised Drinking Water Standard for Arsenic: Small Entity Compliance Guide

EPA 816-R-02-008A

This guide is designed for owners and operators of community water systems (CWSs) and non-transient non-community water systems (NTNCWSs) serving 10,000 or fewer persons. CWSs include all systems (regardless of ownership) serving at least 25 year-round residents or 15 year-round service connections. NTNCWSs include all systems (regardless of ownership) that are not CWSs and that regularly serve at least 25 of the same people for more than 6 months a year. Systems that will typically find this guide useful include:

  • Small towns
  • Rural water districts
  • Tribal systems
  • Mobile home parks
  • Home owners associations
  • Small private systems
  • Factories, religious institutions, and schools that have their own water supplies

Complying With the Revised Drinking Water Standard for Arsenic: Small Entity Compliance Guide (288 KB PDF File, 58 pgs)

 

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