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List of Regulated Toxic Substances and Threshold Quantities for Accidental Release Prevention

77 Substances
(in alphabetical order)

Chemical Name  CAS No.  Threshold (lbs.) 
Acrolein [2-Propenal]  107-02-8 5,000
Acrylonitrile [2-Propenenitrile] 107-13-1 20,000 
Acrylyl chloride [2-Propenoyl chloride] 814-68-6 5,000
Allyl alcohol [2-Propen-l-ol] 107-18-61 15,000
Allylamine [2-Propen-l-amine] 107-11-9 10,000
Ammonia [anhydrous] 7664-41-7 10,000
Ammonia (conc 20% or greater) 7664-41-7 20,000
Arsenous trichloride 7784-34-1 15,000
Arsine 7784-42-1 1,000
Boron trichloride [Borane, trichloro-] 10294-34-5 5,000
Boron trifluoride [Borane, trifluoro-] 7637-07-2 5,000 
Boron trifluoride compound with methyl ether (1:1) [Boron, trifluoro [oxybis [metane]]-, T-4- 353-42-4 15,000
Bromine 7726-95-6 10,000
Carbon disulfide 75-15-0 20,000
Chlorine 7782-50-5 2,500
Chlorine dioxide [Chlorine oxide (ClO2)] 10049-04-4 1,000
Chloroform [Methane, trichloro-]  67-66-3 20,000
Chloromethyl ether [Methane, oxybis[chloro-] 542-88-1 1,000
Chloromethyl methyl ether [Methane, chloromethoxy-] 107-30-2 5,000
Crotonaldehyde [2-Butenal] 4170-30-3 20,000
Crotonaldehyde, (E)- [2-Butenal, (E)-] 123-73-9 20,000
Cyanogen chloride 506-77-4 10,000
Cyclohexylamine [Cyclohexanamine] 108-91-8 15,000
Diborane 19287-45-7 2,500
Dimethyldichlorosilane [Silane, dichlorodimethyl-] 75-78-5 5,000
1,1-Dimethylhydrazine [Hydrazine, 1,1-dimethyl-] 57-14-7 15,000
Epichlorohydrin [Oxirane, (chloromethyl)-] 106-89-8 20,000
Ethylenediamine [1,2-Ethanediamine] 107-15-3 20,000
Ethyleneimine [Aziridine] 151-56-4 10,000
Ethylene oxide [Oxirane] 75-21-8 10,000
Fluorine 7782-41-4 1,000
Formaldehyde (solution) 50-00-0 15,000
Furan 110-00-9 5,000
Hydrazine 302-01-2 15,000
Hydrochloric acid (conc 37% or greater)  7647-01-0 15,000
Hydrocyanic acid 74-90-8 2,500
Hydrogen chloride (anhydrous) [Hydrochloric acid] 7647-01-0 5,000
Hydrogen fluoride/Hydrofluoric acid (conc 50% or greater) [Hydrofluoric acid] 7664-39-3 1,000
Hydrogen selenide 7783-07-5 500 
Hydrogen sulfide 7783-06-4 10,000
Iron, pentacarbonyl- [Iron carbonyl (Fe(CO)5), (TB-5-11)-] 13463-40-6 2,500
Isobutyronitrile [Propanenitrile, 2-methyl-] 78-82-0 20,000
Isopropyl chloroformate [Carbonochloridic acid, 1-methylethyl ester] 108-23-6 15,000
Methacrylonitrile [2-Propenenitrile, 2-methyl-] 126-98-7 10,000
Methyl chloride [Methane, chloro-] 74-87-3 10,000
Methyl chloroformate [Carbonochloridic acid, methylester] 79-22-1 5,000
Methyl hydrazine [Hydrazine, methyl-] 60-34-4 15,000
Methyl isocyanate [Methane, isocyanato-] 624-83-9 10,000
Methyl mercaptan [Methanethiol] 74-93-1 10,000
Methyl thiocyanate [Thiocyanic acid, methyl ester] 556-64-9 20,000
Methyltrichlorosilane [Silane, trichloromethyl-] 75-79-6 5,000
Nickel carbonyl 13463-39-3 1,000
Nitric acid (conc 80% or greater) 7697-37-2 15,000
Nitric oxide [Nitrogen oxide (NO)] 10102-43-9 10,000
Oleum (Fuming Sulfuric acid) [Sulfuric acid, mixture with sulfur trioxide]* 8014-95-7 10,000
Peracetic acid [Ethaneperoxoic acid] 79-21-0 10,000
Perchloromethylmercaptan [Methanesulfenyl chrolide, trichloro-] 594-42-3 10,000
Phosgene [Carbonic dichloride] 75-44-5 500
Phosphine 7803-51-2 5,000
Phosphorus oxychloride [Phosphoryl chloride] 10025-87-3 5,000
Phosphorus trichloride [Phosphorous trichloride] 7719-12-2 15,000
Piperidine 110-89-4 15,000
Propionitrile [Propanenitrile] 107-12-0 10,000
Propyl chloroformate [Carbonochloridic acid, propylester] 109-61-5 15,000
Propyleneimine [Aziridine, 2-methyl-] 75-55-8 10,000
Propylene oxide [Oxirane, methyl-] 75-56-9 10,000
Sulfur dioxide (anhydrous) 7446-09-5 5,000
Sulfur tetrafluoride [Sulfur fluoride (SF4), (T-4)-]  7783-60-0 2,500
Sulfur trioxide 7446-11-9 10,000
Tetramethyllead [Plumbane, tetramethyl-] 75-74-1 10,000
Tetranitromethane [Methane, tetranitro-] 509-14-8 10,000
Titanium tetrachloride [Titanium chloride (TiCl4) (T-4)-] 7550-45-0 2,500
Toluene -2,4-diisocyanate [Benzene, 2,4-diisocyanato-1- methyl-1* 584-84-9 10,000
Toluene -2,6-diisocyanate [Benzene, 1,3-diisocyanato-2- methyl-1]* 91-08-7 10,000
Toluene diisocyanate (unspecified isomer) [Benzene, 1,3- diisocyanatomethyl-]* 26471-62-5 10,000
Trimethylchlorosilane [Silane, chlorotrimethyl-] 75-77-4 10,000
Vinyl acetate monomer [Acetic acid ethenyl ester] 108-05-4 15,000

* The mixture exemption in Section 68.115(b)(1) of the Code of Federal Regulations does
not apply to the substance.


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